Epoxides can be opened under neutral conditions with TMSN3 and TMSCN in the presence of catalyticamounts of Lewis acid, affording the corresponding ring-opened compounds in high yields.
Efficient ring opening of epoxides with trimethylsilylazide and cyanide catalyzed by Erbium (III) Triflate
COSTANZO P;DALPOZZO, Renato;MAIUOLO, Loredana;
2010-01-01
Abstract
Epoxides can be opened under neutral conditions with TMSN3 and TMSCN in the presence of catalyticamounts of Lewis acid, affording the corresponding ring-opened compounds in high yields.File in questo prodotto:
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