The new dinuclear copper(II) metallacyclophanewith the non-innocent N,N0-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a p-stacked anti conformation
The new dinuclear copper(II) metallacyclophane with the non-innocent N,N0-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a p-stacked anti conformation.
Multielectron transfer in a dicopper(II) anthraquinophane
DE MUNNO, Giovanni;ARMENTANO, Donatella
2013-01-01
Abstract
The new dinuclear copper(II) metallacyclophanewith the non-innocent N,N0-1,4-bis(oxamate)-9,10-anthraquinone bridging ligand possesses a dual multielectron redox behavior featuring stepwise one-electron oxidation of the antiferromagnetically coupled CuII ions and two-electron reduction of the anthraquinone spacers in a p-stacked anti conformationI documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
