The reaction of N-(2,6-dimethylphenyl)-oxamic acid with dysprosium(III) ions in a controlled basic media afforded the first example of a mononuclearlanthanide oxamate complex exhibiting a field-inducedslow magnetic relaxation behavior typical of single-ionmagnets (SIMs). The hydrogen-bond-mediated selfassemblyof this new bifunctional dysprosium(III) SIM in the solid state provides a unique example of 2D hydrogen-bonded polymer with a herringbone net topology.
Slow Magnetic Relaxation in a Hydrogen-Bonded 2D Array of Mononuclear Dysprosium(III) Oxamates
DE MUNNO, Giovanni;Armentano D;
2013-01-01
Abstract
The reaction of N-(2,6-dimethylphenyl)-oxamic acid with dysprosium(III) ions in a controlled basic media afforded the first example of a mononuclearlanthanide oxamate complex exhibiting a field-inducedslow magnetic relaxation behavior typical of single-ionmagnets (SIMs). The hydrogen-bond-mediated selfassemblyof this new bifunctional dysprosium(III) SIM in the solid state provides a unique example of 2D hydrogen-bonded polymer with a herringbone net topology.File in questo prodotto:
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