[IrI(CO)(dppm)]2reacts with PhICl2to afford the molecular complex [Ir2Cl2I2(CO)2(μ-dppm)2]. A crystal structure reveals a syn arrangement of chloride as well as carbonyl ligands on adjacents metal atoms. The complex is monoclinic, space group C2/c, with a=43.497(12), b=12.932(3), c=21.619(6) Å,β = 104.26(2)° and Z = 8. © 1993.

Synthesis and structure of the dimer Ir2Cl2I2(CO)2(μ-dppm )2]

Crispini, Alessandra;Ghedini, Mauro;Neve, Francesco
1993-01-01

Abstract

[IrI(CO)(dppm)]2reacts with PhICl2to afford the molecular complex [Ir2Cl2I2(CO)2(μ-dppm)2]. A crystal structure reveals a syn arrangement of chloride as well as carbonyl ligands on adjacents metal atoms. The complex is monoclinic, space group C2/c, with a=43.497(12), b=12.932(3), c=21.619(6) Å,β = 104.26(2)° and Z = 8. © 1993.
1993
Biochemistry; Inorganic Chemistry; Physical and Theoretical Chemistry; Materials Chemistry2506 Metals and Alloys
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/285813
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 9
  • ???jsp.display-item.citation.isi??? ND
social impact