Carbonylation has emerged as the most powerful and sustainable route for the direct incorporation of a carbonyl group into an organic substrate, with formation of high value added molecules starting from readily available substrates and CO, under the catalytic action of a metal complex. With the appropriate catalyst and reaction conditions, starting from suitably functionalized substrates it is possible to synthesize a plethora of heterocyclic derivatives by a carbonylation approach. In this account, I will focus on the most recent achievements realized in my laboratory on the synthesis of heterocycles starting from acetylenic substrates by different types of carbonylations, catalyzed by a very simple and efficient catalytic system, based on palladium iodide in conjunction with potassium iodide.
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|Titolo:||Recent advances in the PdI2-catalyzed carbonylative synthesis of heterocycles from acetylenic substrates: a personal account|
|Data di pubblicazione:||2019|
|Appare nelle tipologie:||2.1 Contributo in volume (Capitolo o Saggio)|