We have investigated linear rheological properties and the structure-flow relationship of the swollen (Lam,) and collapsed (Lam(2)) lamellar phases, formed on didodecyldimethylammonium bromide (DDAB)/lecithin/water ternary system at 25 degrees C. Both lamellar phases behaved like Bingham fluids and showed remarkable yield stresses. At rest the Lam(1) phase, which is characterized by densely packed vesicles whose sizes increase as the water content decreases in accordance to evolution of H-2 NMR spectral profiles of D2O, resulted in a strong elastic gel-like response. On the other hand, the Lam(2) phase, formed at high surfactant concentrations, showed a weak-gel viscoelasticity and H-2 NMR spectral patterns which are typical of planar bilayered structures. The increase of the quadrupole splitting as the water content decreases was assumed as a strong evidence of size increasing of the lamellar domains. We have demonstrated that by using dynamic rheology and the derived relaxation time spectra, along with H-2 NMR spectra of D2O, it is possible to differentiate between equilibrium lamellar structures occurring in a broad interval of total surfactant concentration. In addition, a shear-thickening regime, observed at intermediate shear-rate values, highlighted the onset of out-equilibrium lamellar structures which were present both on Lam(1) and Lam(2) phases.

Swollen and collapsed lyotropic lamellar rheology

COPPOLA, Luigi;NICOTERA, ISABELLA;
2008-01-01

Abstract

We have investigated linear rheological properties and the structure-flow relationship of the swollen (Lam,) and collapsed (Lam(2)) lamellar phases, formed on didodecyldimethylammonium bromide (DDAB)/lecithin/water ternary system at 25 degrees C. Both lamellar phases behaved like Bingham fluids and showed remarkable yield stresses. At rest the Lam(1) phase, which is characterized by densely packed vesicles whose sizes increase as the water content decreases in accordance to evolution of H-2 NMR spectral profiles of D2O, resulted in a strong elastic gel-like response. On the other hand, the Lam(2) phase, formed at high surfactant concentrations, showed a weak-gel viscoelasticity and H-2 NMR spectral patterns which are typical of planar bilayered structures. The increase of the quadrupole splitting as the water content decreases was assumed as a strong evidence of size increasing of the lamellar domains. We have demonstrated that by using dynamic rheology and the derived relaxation time spectra, along with H-2 NMR spectra of D2O, it is possible to differentiate between equilibrium lamellar structures occurring in a broad interval of total surfactant concentration. In addition, a shear-thickening regime, observed at intermediate shear-rate values, highlighted the onset of out-equilibrium lamellar structures which were present both on Lam(1) and Lam(2) phases.
2008
bilayered structures; shear-induced structures; dynamic rheology,; 2H NMR
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/123088
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 41
  • ???jsp.display-item.citation.isi??? 41
social impact