A photophysical, electrochemical and computational study has been performed on a homologous series of cyclometallated Pd(II) (1a-f) and Pt(II) (2a-f) complexes of general formula [(C, N) M(O, O)]; (H(C, N) = azobenzene, 2-phenylpyridine, benzo[ h] quinoline; M = Pd, Pt; H(O, O) = acetylacetone, hexafluoroacetylacetone). Experimental and computational data have shown the strong influence exerted by electronegativity of the ancillary ligand on the frontier orbitals of the complexes, such an effect being enhanced for the Pt(II) species.
Spectroscopy and Electrochemical Properties of Homologous Series of Acetylacetonato and Perfluoro Acetylacetonato Cyclopalladated and Cycloplatinated Complexes / Ghedini, M.; Pugliese, T.; La Deda, M.; Godbert, N.; Aiello, I.; Amati, M.; Belviso, S.; F., Lelj; Accorsi, G.; Barigelletti, F.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - :32(2008), pp. 4303-4318.
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Titolo: | Spectroscopy and Electrochemical Properties of Homologous Series of Acetylacetonato and Perfluoro Acetylacetonato Cyclopalladated and Cycloplatinated Complexes |
Autori: | |
Data di pubblicazione: | 2008 |
Rivista: | |
Citazione: | Spectroscopy and Electrochemical Properties of Homologous Series of Acetylacetonato and Perfluoro Acetylacetonato Cyclopalladated and Cycloplatinated Complexes / Ghedini, M.; Pugliese, T.; La Deda, M.; Godbert, N.; Aiello, I.; Amati, M.; Belviso, S.; F., Lelj; Accorsi, G.; Barigelletti, F.. - In: DALTON TRANSACTIONS. - ISSN 1477-9226. - :32(2008), pp. 4303-4318. |
Handle: | http://hdl.handle.net/20.500.11770/123632 |
Appare nelle tipologie: | 1.1 Articolo in rivista |