Intermolecular proton transfer in solid phase from the hydroxo bridge to a water molecule occurs in a new mu-hydroxo iron(III) compound of formula [EtNH3[Fe2(ox)2Cl2(-OH)]•2H2O]n leading to a still crystalline compound in which the mu-oxo bridge replaces the mu-hydroxo one. Both three-dimensional compounds exhibit magnetic ordering at Tc ca. 70 K due to a spin canting.
Intermolecular Proton Transfer in Solid Phase: A Rare Example of Crystal-to-Crystal Transformation from Hydroxo- to Oxo-Bridged Iron(III) Molecule-Based Magnet
ARMENTANO, Donatella;DE MUNNO, Giovanni;T. F. MASTROPIETRO;
2005-01-01
Abstract
Intermolecular proton transfer in solid phase from the hydroxo bridge to a water molecule occurs in a new mu-hydroxo iron(III) compound of formula [EtNH3[Fe2(ox)2Cl2(-OH)]•2H2O]n leading to a still crystalline compound in which the mu-oxo bridge replaces the mu-hydroxo one. Both three-dimensional compounds exhibit magnetic ordering at Tc ca. 70 K due to a spin canting.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
