Er(OTf3 is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transforination has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be recovered and reused.
A facile Er(OTf)3-catalyzed synthesis of 2,3-unsaturated O- and S- glycosides
DALPOZZO, Renato;DE NINO, Antonio;MAIUOLO, Loredana;
2007-01-01
Abstract
Er(OTf3 is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transforination has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be recovered and reused.File in questo prodotto:
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