Er(OTf3 is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transforination has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be recovered and reused.

A facile Er(OTf)3-catalyzed synthesis of 2,3-unsaturated O- and S- glycosides

DALPOZZO, Renato;DE NINO, Antonio;MAIUOLO, Loredana;
2007-01-01

Abstract

Er(OTf3 is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transforination has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be recovered and reused.
O-Glycosylation; S-Glycosylation; Erbium(III), Triflate
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/124307
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