A metalloporphyrin has been synthesized carrying a beta-cyclodextrin group on tetrafluorophenyl rings at the four meso positions of the porphyrin. It performs the selective hydroxylation of an androstanediol derivative with complete positional selectivity and 187 turnovers.
Geometrically directed selective steroid hydroxylation with high turnover by a fluorinated artificial cytochrome P-450
GABRIELE, Bartolo;
1998-01-01
Abstract
A metalloporphyrin has been synthesized carrying a beta-cyclodextrin group on tetrafluorophenyl rings at the four meso positions of the porphyrin. It performs the selective hydroxylation of an androstanediol derivative with complete positional selectivity and 187 turnovers.File in questo prodotto:
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