A simple synthetic protocol has been developed for the solvent-free cyanosilylation reaction of aldehydes and ketones with trimethylsilylcyanide (TMSCN) catalysed by a new mesoporous silica supported ErIII catalyst. The catalyst can be recovered and reused in subsequent reactions without showing any loss of activity (three uses).
A Mesoporous ErIII-MCM-41 Catalyst for the Cyanosilylation of Aldehydes and Ketones under Solvent-free Conditions
PASQUA, LUIGI
2008-01-01
Abstract
A simple synthetic protocol has been developed for the solvent-free cyanosilylation reaction of aldehydes and ketones with trimethylsilylcyanide (TMSCN) catalysed by a new mesoporous silica supported ErIII catalyst. The catalyst can be recovered and reused in subsequent reactions without showing any loss of activity (three uses).File in questo prodotto:
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