Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T-c values ranging from 40 to 56 K. The value of T-c varies with the cation despite the lack of significant structural modifications.
The cation as a tool in designing spin canted three-dimensional iron(III) networks
ARMENTANO, Donatella;G. DE MUNNO;
2004-01-01
Abstract
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T-c values ranging from 40 to 56 K. The value of T-c varies with the cation despite the lack of significant structural modifications.File in questo prodotto:
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