The linkage isomers [Re(NCS)(6)](2-) and [Re(NCS)(5)(SCN)](2-) are obtained by the reaction of [ReBr(6)](2-) with NCS(-) in dimethylformamide. Some differences in the chemical behavior allowed their separation and structural characterization in the form of (NBu(4))(2)-[Re(NCS)(6)] (1) and [Zn(NO(3))(Me(2)phen)(2)](2)[Re(NCS)(5)(SCN)] (2), respectively (Bu = n-C(4)H(9) and Me(2)phen = 2,9-dimethyl-1,10-phenanthroline).
Linkage Isomerism in the Metal Complex Hexa(thiocyanato)rhenate(IV). Synthesis and Crystal Structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] / R., González; N., Barboza; R., Chiozzone; C., Kremer; Armentano, Donatella; DE MUNNO, Giovanni; J., Faus. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 361(2008), pp. 2715-2720.
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Titolo: | Linkage Isomerism in the Metal Complex Hexa(thiocyanato)rhenate(IV). Synthesis and Crystal Structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] |
Autori: | |
Data di pubblicazione: | 2008 |
Rivista: | |
Citazione: | Linkage Isomerism in the Metal Complex Hexa(thiocyanato)rhenate(IV). Synthesis and Crystal Structure of (NBu4)2[Re(NCS)6] and [Zn(NO3)(Me2phen)2]2[Re(NCS)5(SCN)] / R., González; N., Barboza; R., Chiozzone; C., Kremer; Armentano, Donatella; DE MUNNO, Giovanni; J., Faus. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - 361(2008), pp. 2715-2720. |
Handle: | http://hdl.handle.net/20.500.11770/132195 |
Appare nelle tipologie: | 1.1 Articolo in rivista |