The use of the [ReCl4(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2′ bipyrimidine-bridged ReIV−NiII complex, [ReCl4(μ-bpym)NiBr2(H2O)2] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.
The use of the [ReCl4(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2′-bipyrimidine-bridged ReIV−NiII complex, [ReCl4(μ-bpym)NiBr2(H2O)2] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.
First magneto-structural study on a heterodinuclear 2,2’-bipyrimidine-bridged complex
ARMENTANO, Donatella;DE MUNNO, Giovanni;
2011-01-01
Abstract
The use of the [ReCl4(bpym)] precursor as a ligand toward the fully solvated nickel(II) metal ion affords the first example of a 2,2′ bipyrimidine-bridged ReIV−NiII complex, [ReCl4(μ-bpym)NiBr2(H2O)2] (1), whose intramolecular ferromagnetic coupling has been substantiated from both experimental and theoretical studies.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
