The Cu2+-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.
The Cu2+-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.
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Titolo: | Enantioselective self-assembly of antiferromagnetic hexacopper(II) wheels with chiral amino acid oxamates |
Autori: | |
Data di pubblicazione: | 2013 |
Rivista: | |
Handle: | http://hdl.handle.net/20.500.11770/136290 |
Appare nelle tipologie: | 1.1 Articolo in rivista |