Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkoxycarbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70°C and 100 atm of a 9:1 mixture of carbon monoxide and air.

Novel synthesis of furan-2-acetic esters by palladium-catalysed oxidative cyclization-alkoxycarbonylation of (Z)-2-en-4-yn-1-ols

GABRIELE, Bartolo;
1997

Abstract

Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkoxycarbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70°C and 100 atm of a 9:1 mixture of carbon monoxide and air.
Carbonylation; Heterocycles; Palladium
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11770/138321
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 42
  • ???jsp.display-item.citation.isi??? 44
social impact