We report here the first example of ‘‘sequential homobimetalliccatalysis’’: a transition metal catalyst with the metal in a certainoxidation state catalyses the deprotection of a functional group,which in situ undergoes a subsequent transformation catalysedby another complex of the same metal but in a differentoxidation state.

Sequential Homobimetallic Catalysis: An Unprecedented Tandem Pd(0)-Catalysed Deprotection – Pd(II)-Catalysed Heterocyclisation Reaction Leading to Benzofurans

GABRIELE, Bartolo;MANCUSO R;VELTRI, Lucia
2005

Abstract

We report here the first example of ‘‘sequential homobimetalliccatalysis’’: a transition metal catalyst with the metal in a certainoxidation state catalyses the deprotection of a functional group,which in situ undergoes a subsequent transformation catalysedby another complex of the same metal but in a differentoxidation state.
carbonylation; sequential catalysis; palladium; benzofurans; sequential homobimetallic catalysis; heterocycles
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11770/140274
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