We report here the first example of ‘‘sequential homobimetalliccatalysis’’: a transition metal catalyst with the metal in a certainoxidation state catalyses the deprotection of a functional group,which in situ undergoes a subsequent transformation catalysedby another complex of the same metal but in a differentoxidation state.
Sequential Homobimetallic Catalysis: An Unprecedented Tandem Pd(0)-Catalysed Deprotection – Pd(II)-Catalysed Heterocyclisation Reaction Leading to Benzofurans
GABRIELE, Bartolo;MANCUSO R;VELTRI, Lucia
2005-01-01
Abstract
We report here the first example of ‘‘sequential homobimetalliccatalysis’’: a transition metal catalyst with the metal in a certainoxidation state catalyses the deprotection of a functional group,which in situ undergoes a subsequent transformation catalysedby another complex of the same metal but in a differentoxidation state.File in questo prodotto:
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