Fast-atom bombardment (FAB) mass spectrometry in the negative ionization mode enables the sputtering into the gas phase of the ruthenium complexes [Ru(2,2'-bipyridine[bpy])2(2,5-bis(pyrydil)pyrazine[dpp])](PF6)2; [Ru(bpy)2(2,3-dpp)](PF6)2; [Ru(bpy)2(2,3-dpp-Me)](PF6)3; and [Ru(bpy)2(mu-2,3-dpp)]2RuCl2(PF6)4 as intact radical anions. These data, combined with those available from the positive FAB spectra, allow a full characterization of the analytes. OI sindona, giovanni/0000-0002-5623-5795; SERRONI, Scolastica/0000-0001-7116-9039
REDOX PROCESSES OF RUTHENIUM(II) POLYPYRIDINE COMPLEXES INDUCED BY FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRY
SINDONA, Giovanni;
1993-01-01
Abstract
Fast-atom bombardment (FAB) mass spectrometry in the negative ionization mode enables the sputtering into the gas phase of the ruthenium complexes [Ru(2,2'-bipyridine[bpy])2(2,5-bis(pyrydil)pyrazine[dpp])](PF6)2; [Ru(bpy)2(2,3-dpp)](PF6)2; [Ru(bpy)2(2,3-dpp-Me)](PF6)3; and [Ru(bpy)2(mu-2,3-dpp)]2RuCl2(PF6)4 as intact radical anions. These data, combined with those available from the positive FAB spectra, allow a full characterization of the analytes. OI sindona, giovanni/0000-0002-5623-5795; SERRONI, Scolastica/0000-0001-7116-9039File in questo prodotto:
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