The MacMillan iminium catalyst was investigated for asymmetric Diels-Alder cycloadditions in ionic liquid/H(2)O homogeneous phase. Superior selectivity, product yield, and shorter reaction times were observed in comparison with classical organic solvents. Additional advantages are the easy synthetic procedure, the excellent recovery of products, and the recyclability of the whole system.

A sustainable procedure for highly enantioselective organocatalyzed Diels-Alder cycloadditions in homogeneous ionic liquid/water phase

DE NINO, Antonio;MAIUOLO, Loredana;SINDONA, Giovanni
2011

Abstract

The MacMillan iminium catalyst was investigated for asymmetric Diels-Alder cycloadditions in ionic liquid/H(2)O homogeneous phase. Superior selectivity, product yield, and shorter reaction times were observed in comparison with classical organic solvents. Additional advantages are the easy synthetic procedure, the excellent recovery of products, and the recyclability of the whole system.
Organocatalyst; Ionic liquid; Diels–Alder reaction
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11770/144042
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 32
  • ???jsp.display-item.citation.isi??? 21
social impact