Reactions of N-tritylaspartic acid anhydride, readily available through N,N'-dicyclohexylcarbodiimide-mediated dehydration of N-tritylaspartic acid, with Grignard and Wittig reagents, bulky hydrides, and amines or alcohols of the benzhydryl type, lead regioselectively to products from attack at the beta-carbonyl function.
MODEL STUDIES TOWARDS THE APPLICABILITY OF THE READILY AVAILABLE (S)-N-TRITYLASPARTIC ANHYDRIDE IN THE SYNTHESIS OF AMINO-ACIDS AND PEPTIDES
SINDONA, Giovanni;
1995-01-01
Abstract
Reactions of N-tritylaspartic acid anhydride, readily available through N,N'-dicyclohexylcarbodiimide-mediated dehydration of N-tritylaspartic acid, with Grignard and Wittig reagents, bulky hydrides, and amines or alcohols of the benzhydryl type, lead regioselectively to products from attack at the beta-carbonyl function.File in questo prodotto:
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