Dianions of alpha'-(trimethylsilyl)enaminones can be used as Peterson reagents in the reaction with aldehydes and ketones, to obtain alpha',beta'-unsaturated enaminones or 1,3-diketones with regio and stereocontrol of the new double bond.
A new protocol for the synthesis of alpha',beta'-unsaturated 1,3-diketones
DALPOZZO, Renato;DE NINO, Antonio;
1997-01-01
Abstract
Dianions of alpha'-(trimethylsilyl)enaminones can be used as Peterson reagents in the reaction with aldehydes and ketones, to obtain alpha',beta'-unsaturated enaminones or 1,3-diketones with regio and stereocontrol of the new double bond.File in questo prodotto:
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