Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at Tc values ranging from 40 to 56 K. The value of Tc varies with the cation despite the lack of significant structural modifications.
The Cation as a Tool to Get Spin-Canted Three-Dimensional Iron(III)
D. ARMENTANO;DE MUNNO, Giovanni;T. F. MASTROPIETRO;
2004-01-01
Abstract
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at Tc values ranging from 40 to 56 K. The value of Tc varies with the cation despite the lack of significant structural modifications.File in questo prodotto:
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