A highly efficient oxidative cyclocarbonylation of beta-amino alcohols and 2-aminophenol to oxazolidin-2-ones has been achieved by using PdI2 in conjunction with KI as the catalytic system in DME under relatively mild conditions (100 °C and 20 atm of a 4:1 mixture of CO and air).
AN IMPROVED PROCEDURE FOR THE PALLADIUM-CATALYZED OXIDATIVE CARBONYLATION OF BETA-AMINO ALCOHOLS TO OXAZOLIDIN-2-ONES
GABRIELE, Bartolo;MANCUSO R.;
2003-01-01
Abstract
A highly efficient oxidative cyclocarbonylation of beta-amino alcohols and 2-aminophenol to oxazolidin-2-ones has been achieved by using PdI2 in conjunction with KI as the catalytic system in DME under relatively mild conditions (100 °C and 20 atm of a 4:1 mixture of CO and air).File in questo prodotto:
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