Efficient one-pot three component reaction of aniline derivatives with cyanoamide andtriethyl orthoformate at reflux in toluene affords N0-aryl-N-cyanoformamidines in high yields justby the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by theapplication of this procedure in the synthesis of formamidine pesticides family

Development of one-pot three component reaction for the synthesis of N’-aryl-N-cyanoformamidines, essential precursors of formamidine pesticides family

De Nino A
;
Maiuolo L
;
2016

Abstract

Efficient one-pot three component reaction of aniline derivatives with cyanoamide andtriethyl orthoformate at reflux in toluene affords N0-aryl-N-cyanoformamidines in high yields justby the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by theapplication of this procedure in the synthesis of formamidine pesticides family
Cyanoformamidines; Pesticides; One-pot reaction
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/20.500.11770/155827
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