Efficient one-pot three component reaction of aniline derivatives with cyanoamide andtriethyl orthoformate at reflux in toluene affords N0-aryl-N-cyanoformamidines in high yields justby the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by theapplication of this procedure in the synthesis of formamidine pesticides family
Development of one-pot three component reaction for the synthesis of N’-aryl-N-cyanoformamidines, essential precursors of formamidine pesticides family
De Nino A
;Maiuolo L
;
2016
Abstract
Efficient one-pot three component reaction of aniline derivatives with cyanoamide andtriethyl orthoformate at reflux in toluene affords N0-aryl-N-cyanoformamidines in high yields justby the distillation of the azeotrope toluene/ethyl alcohol. Labelled d9-Amitraz is prepared by theapplication of this procedure in the synthesis of formamidine pesticides familyFile in questo prodotto:
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