The Maier-Saupe model is used to investigate the surface elastic properties of nematic liquid crystals. It is shown that in a surface layer, whose thickness is of the order of the interaction range of the molecular forces responsible for the nematic phase, the elastic constants are position dependent. The theoretical analysis shows that the usual elastic constants reduce a factor two passing from the bulk to the surface and in the expression of the free energy density new elastic terms, arising from the presence of the bounding surface, have to be taken into account. Furthermore it is demonstrated that in the surface layer the splay and twist elastic constants behave in a different manner than the bend elastic constant. The consequences on the modelization of the surface anchoring energy are also discussed. All the calculations are performed by supposing an interaction volume of spherical shape.
SURFACE ELASTIC PROPERTIES OF NEMATIC LIQUID-CRYSTALS
BARBERI, Riccardo Cristoforo;
1994-01-01
Abstract
The Maier-Saupe model is used to investigate the surface elastic properties of nematic liquid crystals. It is shown that in a surface layer, whose thickness is of the order of the interaction range of the molecular forces responsible for the nematic phase, the elastic constants are position dependent. The theoretical analysis shows that the usual elastic constants reduce a factor two passing from the bulk to the surface and in the expression of the free energy density new elastic terms, arising from the presence of the bounding surface, have to be taken into account. Furthermore it is demonstrated that in the surface layer the splay and twist elastic constants behave in a different manner than the bend elastic constant. The consequences on the modelization of the surface anchoring energy are also discussed. All the calculations are performed by supposing an interaction volume of spherical shape.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
