Stoichiometric triethylamine in methanol produces sub-micron ZIF-90 in 98% yield with the largest gas uptakes ever measured. Micropore volume and surface area are compatible with an empty pore network and with crystallographic data, but the occurrence of crystal defects, such as missing ligands or Zn 2+ ions, although improbable, can not be ruled out.
Synthesis and gas sorption behaviour of ZIF-90 with large pore volume
Liguori, Paola F.;Russo, Beatrice;Melicchio, Alessandro;Golemme, Giovanni
2017-01-01
Abstract
Stoichiometric triethylamine in methanol produces sub-micron ZIF-90 in 98% yield with the largest gas uptakes ever measured. Micropore volume and surface area are compatible with an empty pore network and with crystallographic data, but the occurrence of crystal defects, such as missing ligands or Zn 2+ ions, although improbable, can not be ruled out.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
