The mixed Ir-Cu complex, [IrCI(PPh3)2(dppn)(NO)CuCI][PF6]2 [dppn = 3,6-bis(2'-pyridyl)pyridazine], has been synthesised starting from [Ir(NO) (dppn),(PPh3)] [PF6]2, a complex with a linearly bound nitrosyl group; X-ray structural analysis has shown that both dppn and nitrosyl ligands bridge the metal atom and this is the first example of a nitrosyl group bridging two different metals
Synthesis and crystal structure of the mixed iridium(III) and copper(II) complex, [IrCl(PPh3)2(µ-dppn)(µ-NO)CuCl][PF6]2, [dppn = 3,6-bis(2′-pyridyl)pyridazine], with a nitrosyl group bridging two different metals
Ghedini, Mauro;Neve, Francesco
1983-01-01
Abstract
The mixed Ir-Cu complex, [IrCI(PPh3)2(dppn)(NO)CuCI][PF6]2 [dppn = 3,6-bis(2'-pyridyl)pyridazine], has been synthesised starting from [Ir(NO) (dppn),(PPh3)] [PF6]2, a complex with a linearly bound nitrosyl group; X-ray structural analysis has shown that both dppn and nitrosyl ligands bridge the metal atom and this is the first example of a nitrosyl group bridging two different metalsFile in questo prodotto:
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