A scries of three 4,4′-disubstituted-2,2′-bipyridines and the corresponding mononuclear cis-dichloro palladium(II) complexes have been synthesized None of the ligands show mesomorphisrn. Upon their complexation to Pd(II) the peculiar structural arrangement characterized by intermolecular associations of the new derivatives induces mesogenic properties, confirming the new and exciting role of the coordination chemistry in metal-mediated formation of liquid crystals.

Induction of mesomorphism through supramolecular association in coordination Pd (II) compounds of dialkyl 2,2′-bipyridine-4,4′-dicarboxylates

Pucci, Daniela;BARBERIO, Giovanna;Crispini, Alessandra;Ghedini, Mauro;
2003-01-01

Abstract

A scries of three 4,4′-disubstituted-2,2′-bipyridines and the corresponding mononuclear cis-dichloro palladium(II) complexes have been synthesized None of the ligands show mesomorphisrn. Upon their complexation to Pd(II) the peculiar structural arrangement characterized by intermolecular associations of the new derivatives induces mesogenic properties, confirming the new and exciting role of the coordination chemistry in metal-mediated formation of liquid crystals.
2003
Coordination compounds; Dialkyl 2.2′-bipyridine-4.4′-dicarboxylates; Metallomesogens; Palladium; Chemistry (all); Materials Science (all); Condensed Matter Physics
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/285412
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 24
  • ???jsp.display-item.citation.isi??? 28
social impact