[IrI(CO)(dppm)]2reacts with PhICl2to afford the molecular complex [Ir2Cl2I2(CO)2(μ-dppm)2]. A crystal structure reveals a syn arrangement of chloride as well as carbonyl ligands on adjacents metal atoms. The complex is monoclinic, space group C2/c, with a=43.497(12), b=12.932(3), c=21.619(6) Å,β = 104.26(2)° and Z = 8. © 1993.
Synthesis and structure of the dimer Ir2Cl2I2(CO)2(μ-dppm )2]
Crispini, Alessandra;Ghedini, Mauro;Neve, Francesco
1993-01-01
Abstract
[IrI(CO)(dppm)]2reacts with PhICl2to afford the molecular complex [Ir2Cl2I2(CO)2(μ-dppm)2]. A crystal structure reveals a syn arrangement of chloride as well as carbonyl ligands on adjacents metal atoms. The complex is monoclinic, space group C2/c, with a=43.497(12), b=12.932(3), c=21.619(6) Å,β = 104.26(2)° and Z = 8. © 1993.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
