The X-ray crystal structure of the cyclometallated palladium(II) complex [Pd(L2)(μ-Cl)2], L2=2,6-dimethyl-N- (benzylidene)phenylaminate, is described. Crystals were orthorhombic, space group Pna21with a = 17.307(3) Å, b = 17.732(4) Å, c = 9.075(2) Å, Z = 4, U = 2785.0(10) Å3. The palladated dimer, with asymmetrically bridging chlorine atoms, exhibits a Pd2Cl2unit folded at 36.7(1)° and a non-bonding Pd ⋯ Pd separation of 3.425(1) Å. © 1992.
Cyclopalladated complexes. Synthesis and crystal structure of di-μ-chloro-bis[2,6-dimethyl-N-(benzylidene) phenylaminato-C2′, N]palladium(II)
Crispini, Alessandra;De Munno, Giovanni;Ghedini, Mauro;Neve, Francesco
1992-01-01
Abstract
The X-ray crystal structure of the cyclometallated palladium(II) complex [Pd(L2)(μ-Cl)2], L2=2,6-dimethyl-N- (benzylidene)phenylaminate, is described. Crystals were orthorhombic, space group Pna21with a = 17.307(3) Å, b = 17.732(4) Å, c = 9.075(2) Å, Z = 4, U = 2785.0(10) Å3. The palladated dimer, with asymmetrically bridging chlorine atoms, exhibits a Pd2Cl2unit folded at 36.7(1)° and a non-bonding Pd ⋯ Pd separation of 3.425(1) Å. © 1992.File in questo prodotto:
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