Experimental determination of TDR calibration relationship for pyroclastic ashes of campania (Italy)

Time domain reflectometry (TDR) is one of the most widely used techniques for indirect determination of soil volumetric water content (θ). TDR measures the relative dielectric constant (εr ) which, in a three-phase system like the soil, depends on water, air, and solid matrix dielectric constants. Since dielectric constant of water is much larger than the other two, εr of bulk soil mainly depends on water content. In many cases, the application of TDR requires a specific calibration of the relationship θ(εr ) to get quantitatively accurate estimates of soil water content. In fact, the relationship θ(εr ) is influenced by various soil properties, such as clay content, organic matter content, bulk density, and aggregation. Numerous studies have shown that pyroclastic soils often exhibit a peculiar dielectric behavior. In Campania (Southern Italy) wide mountainous areas are covered by layered pyroclastic deposits of ashes (loamy sands) and pumices (sandy gravels), often involved in the triggering of landslides induced by rainwater infiltration. Reliable field measurements of water content of such soils are therefore important for the assessment of landslide risk. Hence, in this paper, the θ(εr ) relationship has been experimentally determined on samples of typical pyroclastic soil of Campania, collected around Sarno, reconstituted with different porosities. The aim of the study is to identify specific calibration relationships for such soils based not only on empirical approaches. In this respect, a three-phase dielectric mixing model with a variable exponent is introduced, and the variable value of the exponent is related to the different dielectric properties of bond and free water within the soil pores.