The complex [ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air. © 2012 American Chemical Society.
Pyro without fire: Synthesis, structure, and reactivity of a dimeric vanadyl pyrophosphate coordination complex
Marino, Nadia
;
2012-01-01
Abstract
The complex [ (V IVO)bipy(H 2O)] 2(μ- P 2O 7)3H 2O (2) was readily obtained as a nanocrystalline powder by one-pot synthesis under mild conditions. Single crystals of 2 were grown at room temperature over 2 months, and its structure was determined. Fundamental catalytic activity was proven for this species by testing for oxidation of benzyl alcohol in air. © 2012 American Chemical Society.File in questo prodotto:
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