Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocy-cle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.
Alkene epoxidations mediated by mn-salen macrocyclic catalysts
Veltri L.;
2021-01-01
Abstract
Three new chiral Mn macrocycle catalysts containing 20 or 40 atoms in the macrocy-cle were synthetized and tested in the enantioselective epoxidation of cis-β-ethyl-styrene and 1,2-dihydronathalene. The effect of the presence of a binaphtol (BINOL) compound in the catalyst backbone has been evaluated, including by Density Functional Theory (DFT) calculations.File in questo prodotto:
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