Building materials and decay assessment of the Gerace Cathedral (Reggio Calabria, Southern Italy)

A multi-analytical approach was employed for the first time to study the stone materials, wall paintings and related degradation forms in the Cathedral of Gerace (Reggio Calabria, southern Italy). With an area of around 1898 square meters, the Gerace Cathedral is the largest in Calabria: its construction dates back to the Norman era (between 1085 and 1120), and currently displays distinct features of Greek and Latin architectural orders. Despite having undergone numerous restorations, the church perfectly preserves its original buildings materials. Following an extensive site inspection campaign, supported by the experts dealing with building restoration, several areas were selected for analyses. Both in situ investigations and laboratory tests were carried out on micro-fragments using Non-Destructive and Micro-Destructive Techniques (NDTs and MDTs). The first step involved an inspection through InfraRed Thermography (IRT) in order to map the internal walls of the Cathedral and identify zones with potential degradation phenomena. Subsequently, a more in-depth study was designed based on the thermographic results, and laboratory tests were carried out on micro-fragments and powders to characterize the different kinds of materials (i.e., stones, mortars, plasters and pigments) and decay agents (i.e., salts and efflorescences). Thirty-one samples were subjected to a complementary analytical approach which included Polarizing Optical Microscopy (POM), Ion Chromatography (IC), X-Ray Powder Diffraction (XRPD) and Scanning Electron Microscopy (SEM) coupled with microanalysis (EDS). The results allowed us to preliminarily characterize the different materials from which the Cathedral was built, determine its state of conservation and provide a better knowledge of the entire building, revealing details not visible to the naked eye which are important for future conservation interventions. As for the state of conservation, the integrated use of various techniques enabled the detection of rising damp generally correlated with the occurrence of water infiltration and migration phenomena which appear to affect a large part of the building, causing noticeable damage (i.e., loss of surface material, micro-cracks, white salt efflorescence, etc.). The characterization of the materials carried out on mortars, plasters, and pigments also confirmed the local origin of the raw materials. However, the provenance of the studied marbles and crystalline limestones, could not be established and, therefore, further in-depth studies are required.