An iron -catalyzed oxidative aminocarbonylation of alkyl boronic pinacol esters via alkyl radical intermediate has been developed. Various aliphatic amides were produced in good yields from the corresponding alkyl boronic esters and anilines in the presence of oxidant under carbon monoxide pressure.

Iron-Catalyzed carbonylative synthesis of amides from Alkyl-Boronic pinacol ester via a single electron transfer process

De Salvo, Alex;Mancuso, Raffaella
;
2024-01-01

Abstract

An iron -catalyzed oxidative aminocarbonylation of alkyl boronic pinacol esters via alkyl radical intermediate has been developed. Various aliphatic amides were produced in good yields from the corresponding alkyl boronic esters and anilines in the presence of oxidant under carbon monoxide pressure.
2024
Carbonylation
Iron catalyst
Amide
Oxidative coupling
Radical intermediate
Alkyl boronic pinacol ester
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/365131
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