A novel and straightforward route to steroidal Z- and E-enol aldehydes is presented. Acid-catalysed treatment allows formal dismutation of corticosteroids, affording good yields of the related enol compounds which can be easily separated and purified.
A novel and straightforward route to steroidal Z- and E-enol aldehydes is presented. Acid-catalysed treatment allows formal dismutation of corticosteroids, affording good yields of the related enol compounds which can be easily separated and purified. (C) 2001 Elsevier Science Ltd. All rights reserved.
A facile approach to steroidal 20-hydroxy-17(20)-en-21-aldehydes: important intermediates in the biological 17-dehydroxylation of C-17 dihydroxyacetone steroids
DI GIOIA, Maria Luisa;LEGGIO, Antonella;LIGUORI, Angelo;NAPOLI, Anna Maria Carmela Natale V;SICILIANO, Carlo;SINDONA, Giovanni
2001-01-01
Abstract
A novel and straightforward route to steroidal Z- and E-enol aldehydes is presented. Acid-catalysed treatment allows formal dismutation of corticosteroids, affording good yields of the related enol compounds which can be easily separated and purified.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
