Er(OTf)3 in 2-MeTHF provides a new and eco-friendly process for Ferrier glycosylation ofsulfonamides and amino acids with various N-nucleophiles.The stereoselective synthesis of 2,3-unsaturated-N-pseudoglycals was carried out with 3,4,6-tri-O-acetyl-D-glucal and different nucleophiles affording good results in a short time.

An eco-friendly tandem tosylation/Ferrier N-glycosylation of amines catalyzed by Er(OTf)3 in 2-MeTHF

DE NINO, Antonio;DI GIOIA, Maria Luisa;MAIUOLO, Loredana;
2017-01-01

Abstract

Er(OTf)3 in 2-MeTHF provides a new and eco-friendly process for Ferrier glycosylation ofsulfonamides and amino acids with various N-nucleophiles.The stereoselective synthesis of 2,3-unsaturated-N-pseudoglycals was carried out with 3,4,6-tri-O-acetyl-D-glucal and different nucleophiles affording good results in a short time.
2017
2-MeTHF ; Glycosydation; Sulfonamidoglycosides.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11770/144990
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